I'm not sure if ConnectShare uses DLNA, is this the feature wherein you can stream from your other android device to your tv?
But still, Samsung utilizes DLNA in order to discover shared media in the network.
I use XBMC on my PC since Windows Media Player has limitations when it comes to media sharing. I can play all my media files on the tv. Ang prob lang yung mga high bitrate na MKVs minsan nagbubuffer kasi wireless lang connection ko. Siguro kung nakawired na sya hindi na, kaso tinatamad akong maglatag ng wire...
And to add, DLNA is an industry standard (started by Sony i think
), that's why I said on my previous post that your NAS has to have a DLNA server on it.