Timbre matching can be a difficult exercise between different brands or even between different models in the same brand. For one, room accoustic conditions that have different diffractive and absorptive qualities adjacent to speakers can also affect the timbre between identical speakers, so they can sound different. The safest bet and one often advised is to AT LEAST use identical speakers in the same brand or model. And to make the room accoustics identical between left and right speakers, and also betwen front and back. But this is rarely possible in the real world. So having identical speakers in the same model would at least minimize timbral differences in a real room with disparate accoustic conditions where you put the speakers.
I can understand the situation where you start with front L and R speakers, then expand to 5.1 later with the addition of other speakers. Sometimes, if you wait long enough, the matching center and surround models may have changed in design or discontinued. In cases like this, you will have to use aural discretion. SPL meters can only check amplitudes, not the harmonics and overtones coming from a speaker that distinguishes their timber qualities or sonic coloration. Unless you have an expensive spectrum analyzer.
Also, trimbral difference between speakers do not exist uniformly across the audio spectrum. It's possible two speakers may have the same timbral qualities in the low-mids or high mids, but different elsewhere. It's possible that a ferrari engine sounds the same across two different speaker brands, but try a jet engine roar and there could be differences.
The best way to test is to use pink noise test. Correlated pink noise, meaning in mono, contain frequencies from 20hz to 20khz. They should give you an indication of the speaker's timbral qualities or sonic coloration (timbre and coloration in speakers mean the same thing). Most AVRs have pink noise and some DVD players also have this. If not, you can use some DVD or CD test discs with pink noise in one of their tracks. The noise in between FM stations contain most of these freqeuncies and can be recorded for this purpose. Do some AB comparative test and let your ears decide if the difference is objectionable, acceptable or none