Hi & welcome aboard to this great forum chiemonyo
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Bro are you referring to a upscale/upconvert DVD player or actual high definition HDTV? I presume you meant the ealier. To answer some of your questions:
1. All current DVDs player & TVs have the component connections so you don't need any adapter. You can connect direct from your player to the TV. Btw, I never seen a DVI-Component adapter & don't think such adapter is available.
2. Your WS 32" Samsung Slim Fit has component input so this should give you the best possible PQ.
3. Either using a componet progressive scan or HDMI connection from an upscale player to a 32" tv, it's very hard to notice any difference due to the small screen size (we had tried on a BIG projector screen & still find it hard to spot any improvement). Overall, PQ will still look the same unless you are actually playing a HD movie. Samsung is capable of displaying up to 1080i.
4. For a 32" tv, any average player with component progressive should do fine. Current HDMI cable is very expensive, averaging around 6k. It's really meaningless to use HDMI on a upscale player as the actual movie source isn't in HD.